The EIMS fragmentation mechanisms of the sesquiterpenes corvol ethers A and B, epi-cubebol and isodauc-8-en-11-ol
نویسندگان
چکیده
Farnesyl diphosphate (FPP) and all fifteen positional isomers of ((13)C1)FPP were enzymatically converted by the bacterial terpene cyclases corvol ether synthase from Kitasatospora setae, the epi-cubebol synthase from Streptosporangium roseum, and the isodauc-8-en-11-ol synthase from Streptomyces venezuelae. The enzyme products were analysed by GC-MS and GC-QTOF MS(2) and the obtained data were used to delineate the EIMS fragmentation mechanisms of the two sesquiterpene ethers corvol ethers A and B, and the sesquiterpene alcohols epi-cubebol and isodauc-8-en-11-ol.
منابع مشابه
Halogenated terpenes and a C(15)-acetogenin from the marine red alga Laurencia saitoi.
Seven parguerane diterpenes: 15-bromo-2,7,19-triacetoxyparguer-9(11)-en-16-ol (1), 15-bromo-2,7,16,19-tetraacetoxyparguer-9(11)-ene (2), 15-bromo-2,19-diacetoxyparguer-9(11)-en-7,16-diol (3), 15-bromo-2,16,19-triacetoxyparguer-9(11)-en-7-ol (4), 15-bromo-2,16-diacetoxyparguer-9(11)-en-7-ol (5), 15-bromoparguer-9(11)-en-16-ol (6), 15-bromoparguer-7-en-16-ol (7), two polyether triterpenes: thyrsi...
متن کاملSesquiterpenes from Laurencia similis.
One new sesquiterpene, (4E)-1-bromo-5-[(1'S*,3'R*)-3'-bromo-2',2'-dimethyl-6'-methylenecyclohexyl]-3-methylpent-4-ene-2,3-diol (1), and fifteen known sesquiterpenes, isopalisol (2), luzonensol (3), palisadin B (4), aplysistatin (5), palisadin A (6), 4-hydroxyl-palisudin C (7), 5-acetoxypalisadin B (8), 10-hydroxyaristolan-9-one (9), aristol-8-en-1-one (10), aristolan-9-en-1-one (11), aristolan-...
متن کاملSeasonal Variation of Mono- and Sesquiterpenes in the Essential Oil of Pycnocycla Spinosa Decne. ex Boiss.
Pycnocycla spinosa aerial parts were collected weekly during four-month growth. Hydrodistillation and gas chromatography coupled with mass spectroscopy techniques were used for essential oil and sesquiterpenes investigation. Thirty-four components were identified, of which the characteristic sesquiterpenes were a -copaene, caryophyllene, a -humulene, b-ionene, d-cadinene, a -calacorene, caryoph...
متن کاملSeasonal Variation of Mono- and Sesquiterpenes in the Essential Oil of Pycnocycla Spinosa Decne. ex Boiss.
Pycnocycla spinosa aerial parts were collected weekly during four-month growth. Hydrodistillation and gas chromatography coupled with mass spectroscopy techniques were used for essential oil and sesquiterpenes investigation. Thirty-four components were identified, of which the characteristic sesquiterpenes were a -copaene, caryophyllene, a -humulene, b-ionene, d-cadinene, a -calacorene, caryoph...
متن کاملEffect of Phosalone on Testicular Tissue and In Vitro Fertilizing Potential
Background The current study aimed to evaluate the effects of phosalone (PLN) as an organophosphate (OP) compound on testicular tissue, hormonal alterations and embryo development in rats. MaterialsAndMethods In this experimental study, we divided 18 mature Wistar rats into three groups-control, control-sham and test (n=6 per group). Animals in the test group received one-fourth the lethal dose...
متن کامل